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Q.

 If dxdt=kH3O+nand rate become 100 times when pH changes form 2 to 1. Hence order of reactions is 

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a

2

b

1

c

0

d

3

answer is B.

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Detailed Solution

pH-21 rate-r100r                             We know that, pH=-logH+=-logH3O+                             H3O+=?                             2=-logH3O+                             H3O+=10-2                             Similarly, when pH=1, then H3O+=10-1                             substituting the above values in rater=kH3O+n equation                             we have, r1=k10-2n=r                             r2=k10-1n=100 r                             r2r1=100=10-110-2n                               102=10n                                n=2

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