Q.

If EBrO,BrO3,OHPt=0.54V and EBrO,Br2,OHPt=0.45V the E value of the half-cell BrO3,Br2,OHPt will be 

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a

0.99 V

b

0.52 V

c

0.25 V

d

0.09 V

answer is A.

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Detailed Solution

BrO3+2H2O+4eBrO+4OH    E=0.54VBrO+H2O+e12Br2+2OH    E=0.45V

For the given half-cell, the reaction is 

BrO3+3H2O+5e12Br2+6OH E=?

This reaction is obtained by adding the first two reactions 

Hence, 5FE=4F(0.54V)1F(0.45V)  E=0.52V

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