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Q.

If ECr2+,Cr3+Pt=0.42V and ECr2+Cr=0.90V then E for the half-cell Cr3+Cr will be

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a

1.32V

b

0.74V

c

0.74V

d

0.48V

answer is C.

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Detailed Solution

Add Cr3++eCr2+ ΔG1=(1)F(0.42V)Cr2++2eCr ΔG2=(2)F(0.90V)Cr3++3eCr¯ ΔG3=F(0.422×0.90)V¯  

Also ΔG30=3FECr3+Cr Hence 3ECr3+Cr=2.22V or E=0.74V

 

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If E∘Cr2+,Cr3+∣Pt=−0.42V and E∘Cr2+∣Cr=−0.90V then E∘ for the half-cell Cr3+∣Cr will be