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Q.

If K1 and K2 are the equilibrium constants of equilibria A and B respectively, then the relationship between the two constants is

(A) SO2( g)+12O2( g)SO3( g)K1

(B) 2SO3( g)2SO2( g)+O2( g)K2

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a

K1=1 K2

b

K2=K12

c

K1=K2

d

K12=1 K2

answer is D.

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Detailed Solution

 (A) SO2( g)+12O2( g)SO3( g)K1

(B) 2SO3( g)2SO2( g)+O2( g)K2

 

 For reaction (A), K1 is reserved and for reaction (B), K2 is reserved. Now, the reaction, (C), SO3(g)SO2(g)+1/2O2(g)K3 is obtained. The relationship between K1 and K3 is K1=1K3

When equilibrium (C), K3 is multiplied by 2. So, the relationship between K2 and K3 is 1K2=(1K3)2

Thus, 1K2=(1/K3)2=K21

Therefore, the correct answer is option (D)K12=1 K2.

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