Q.

If O2 gas is bubbled through water at 303 K, the number of millimoles of  O2 gas that dissolve in 1 litre of water is __________(Nearest Integer)

(Given: Henry’s law constant for O2 at 303 K is 46.82 k bar and partial pressure of  O2=0.920  bar) (Nearly negligible)

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Detailed Solution

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Complete Solution:

Using Henry's Law:

x = p / KH

where:

  • p = 0.920 bar,
  • KH = 46.82 × 103 bar.

x = 0.920 / (46.82 × 103) = 1.965 × 10-5.

Number of moles of water in 1 liter (assuming density = 1 g/mL):

Moles of water = 1000 g / 18 g/mol = 55.56 mol.

Moles of O2 = x × 55.56 = 1.965 × 10-5 × 55.56 = 1.09 × 10-3 mol.

1.09 × 10-3 mol × 1000 = 1.09 mmol.

Final Answer

1 mmol

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