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Q.

If S+02SO2; H=-3982 kJ;  SO2+12O2SO3; H=-98.7kJ SO3+H2OH2SO4; H=-130.2kJ; H2+12O2H2O; H=-227.3kJThe enthalpy of formation of sulphuric acid at 298K will be

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a

-854.4 kJ

b

-754.4 kJ

c

-650.3 kJ

d

-433.7 kJ

answer is A.

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Detailed Solution

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S+O2SO2 ΔH=398.2kJ..(1)SO2+12O2SO3 ΔH=98.7kJ..2SO3+H2OH2SO4 ΔH=130.2kJ.....3H2+12O2H2O ΔH=227.3kJ.4

H2+S+2O2H2SO4 ΔH=854.4kJ

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