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Q.

If S+O2 SO2 ; ΔH= 398.2 KJ 

SO2+12O2SO3 ; ΔH=98.7 KJ 

SO3+H2O H2SO4; ΔH=130.2 KJ 

H2+12O2H2O ; ΔH=227.3 KJ 

The enthalpy of formation of sulphuric acid at 298 K will be

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a

-754.4 KJ

b

-650.3 KJ

c

-433.7 KJ

d

-854.4 KJ

answer is A.

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Detailed Solution

S+O2SO2 ΔH=398.2kJ..(1)SO2+12O2SO3 ΔH=98.7kJ..2SO3+H2OH2SO4 ΔH=130.2kJ.....3H2+12O2H2O ΔH=227.3kJ.4

 The required reaction is:

H2+S+2O2H2SO4 

This reaction can be obtained by adding (i), (ii), (iii), and (iv).

The enthalpy of the reaction will be:

ΔH=-398.2-98.7-130.2-227.3=-854.4 KJ 

Therefore, the correct option is A.

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