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Q.

If z-axis be the internuclear axis, which of the following combination of orbitals would not form  π-bond?

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a

d2x+d2x

b

dyz+dyz

c

px+px

d

dxy+dxy

answer is B.

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Detailed Solution

dxy−dxy form  π-bond if z-axis is the internuclear axis.

Atomic orbitals connect in a sideways positive (same phase), perpendicular to the internuclear axis direction, to generate pi bonds.

Hence, the option B is correct.

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