Q.

In Arrhenius equation for a certain reaction, the values of A and Ea  (activation energy) are4×1013sec1 and 98.6KJ mol1 respectively. The specific rate constant is1.1×103s1 then temperature is

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a

100.9 K

b

320.7 K

c

210.9 K

d

310.96 K

answer is A.

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Detailed Solution

According to Arrhenius equation,

k=A.eEa/RT

Apply ln on both sides in the above equation.

lnk=lnAEaRT

Now, convert ln into log by multiply with 2.303

2.303 log10k=2.303 log10AEaRT

Substitute the given data in this equation to find temperature of a reaction.

2.303 log(1.1×103)=2.303log(4×1013)98.6×1038.314×T

After solve the above equation we will get

T=98.6×1038.314×2.303×16.56=310.96 K

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