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Q.

In the precipitation of sulphides of second group of basic radicals. H2S is passed into the acidified solution with dilute HCl. If the solution is not acidified, then which is the correct statement?

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a

Only the sulphides of second group get precipitated

b

Neither of the sulphides of second and fourth groups get precipitated

c

Only the sulphides of fourth group get precipitated

d

Sulphides of both the groups get precipitated.

answer is D.

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Detailed Solution

(d) In the absence of dilute HCl. Ionization of H2S is not suppressed due to common ion effect. As a result, [S2] increases to such an extent that fourth group sulphides having higher Ksp values also get precipitated.

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