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Q.

In 1 L saturated solution of AgCl, Ksp(AgCl)=1.6×1010 0.1 mole of CuClKsp(CuCl)=1.0×106 is added. The resultant concentration of Ag+ in the solution is 1.6 x 10 - x. The value of x is

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answer is 7.

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Detailed Solution

It is a case of simultaneous solubitity of salts with a common ion. Here ,solubility product of CuCl is much greater than that of AgCl, it can be assumed that Cl- in solution comes mainly from CuCl.
Cl=Ksp(CuCl)=103M
 For AgCl,Ksp=1.6×1010
=Ag+Cl =Ag+×103 =Ag+=1.6×107 

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In 1 L saturated solution of AgCl, Ksp(AgCl)=1.6×10−10 0.1 mole of CuClKsp(CuCl)=1.0×10−6 is added. The resultant concentration of Ag+ in the solution is 1.6 x 10 - x. The value of x is