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Q.

In a cell, the following reactions take place

Fe2+Fe3+e    EFe3+/Fe2+=0.77V2II2+2e       EI2/I=0.54V

The standard electrode potential for the spontaneous reaction in the cell is x × 10–2 V 298
K. The value of x is __________ (Nearest Integer)

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answer is 23.

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Detailed Solution

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 Fe+3Cathode+IanodeI2+Fe+2 ECell0=Ecathode0Eanode0 =0.770.54 =0.23 =23×102V

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