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Q.

In a chemical reaction, A+2BK2C+D,the initial concentration of B was 1.5 times of the concentration of A.  but the equilibrium concentrations of A and B were found to be equal.  The equilibrium constant (K) for the aforesaid chemical reaction is:

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a

16

b

4

c

1

d

1/4

answer is B.

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Detailed Solution

A            +           2B     K    2C    +    D

t=0  a0  1.5a0       0 0

t=teq (a0X)   (1.5a02x)  2x x

Given at equilibrium [A]=[B]

a0x1.5a02x

x0.5a0  or  =2x

Equilibrium constant k=[C]2[D][A][B]2

k=(2x)2(x)(a0x)(1.5a02x)

k=(2x)2(0.5a0)(a00.5a0)(1.5a0a0)2

k=0.5a020.5a0(0.5a0)2=4

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