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Q.

In a closed container two reactions take place simultaneously

 (i) PCl5(g)PCl3(g)+Cl2(g) and

 (ii) CO(g)+Cl2(g)COCl2(g)

On adding more CO into the container, select the correct options :

(P) Degree of dissociation of PCl5(g) decrease 

Q) Cone. of CO(g) at new equilibrium position i less than that of at initial equilibrium cone.

(R) Degree of dissociation of PCl5(g)  increases.

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a

Both (Q) and (R)

b

Only (R)

c

Only (P)

d

Both (P) and (Q)

answer is B.

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Detailed Solution

On adding more CO, reaction (ii), goes forward, thus decreasing [Cl2]. Hence, reaction (i) moves forward,
 [PCl5] and [PCl3]α
 

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In a closed container two reactions take place simultaneously (i) PCl5(g)⇌PCl3(g)+Cl2(g) and (ii) CO(g)+Cl2(g)⇌COCl2(g)On adding more CO into the container, select the correct options :(P) Degree of dissociation of PCl5(g) decrease Q) Cone. of CO(g) at new equilibrium position i less than that of at initial equilibrium cone.(R) Degree of dissociation of PCl5(g)  increases.