Q.

In a constant pressure calorimeter with heat capacity of  450JK1, 200 ml of 0.9 M HCl  and 200 ml of 0.45 M  Ba(OH)2 are mixed. The density of  final solution is 1gm  ml-1   .  Initially, both solutions are at 21C . Select correct statement  [Given:ΔHNeutralization=56.2kJ  mol1]
Specific heat of H2O=4.184Jgm1  .
 

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a

ΔH  of reaction is  10.116×103J

b

Final temperature is  25.76C

c

Some HCl is left unreacted

d

Some Ba(OH)2 is left unreacted

answer is A, C.

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Detailed Solution

Mole  of  HCl=200×0.91000=0.18 Mole  of  OH=200×(0.45×2)1000=0.18 Thus, [H+]=[OH]  hence no reactant is left unreacted ΔfH=(0.18)(56.2kJmol1)=10.116kJ ΔHcalorimeter=CpΔT   =450×ΔT ΔHsolution=m.s.ΔT=400×4.184×ΔT ΔHtotal=450ΔT+1673.6ΔT 10.116×103=2123.6ΔT   ΔT=101162123.6=4.7636K4.76 T2=4.76+21=25.76C

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