Q.

In a first order reaction, 20 % reaction is completed in 24 minutes. The percentage of reactant remaining after 48 minutes is

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a

60

b

81

c

40

d

80

answer is B.

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Detailed Solution

For a first order reaction:

k=2.303tlogaa-x Case (1) : k=2.303tlog10010060  =2.30320log10040 =2.30320(log10log4) =2.30320(10.6020) =0.046 Case (ii) : k=2.303tlog10010084  t=2.3030.046log10016 =2.3030.046(log100log16) =2.3030.046(21.2041) =39.84min=40min

 

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