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Q.

In a Ist order reaction: A products, the concentration of the reactant decreases to 6.25% of its initial value in 80 minutes. What is (i) the rate constant and (ii) the rate of the reaction, 100 minutes after the start, if the initial concentration is 0.2mole/litre ?

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a

2.17×102min1,3.47×104mol litre 1min1

b

3.465×102min1,2.166×104mol1 litre 1  min1.

c

3.465×103min1,2.17×103mol litre 1min1 

d

2.166×103min1,2.667×104 mol-litre 1 min1

answer is B.

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Detailed Solution

k×80=ln1006.25

(a) k=3.465×102min1

(b) [A]4=0.2×e3.465×109×100=6.25×103

r=k[A]t=2.167×104moll1min1

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