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Q.

In a metal oxide, oxide ions are arranged in a hcp array and the metal ion occupies octahedral holes. If one-third of octahedral voids and all tetrahedral voids are empty the metal oxide formula is (M- metal)

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a

MO2

b

M2O3

c

M3O2

d

MO

answer is B.

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Detailed Solution

It is provided that oxide ions are arranged in HCP  and we know that in HCP there are 6 oxide ions per unit cell. 

Numbers of octahedral voids = no. of atom per unit cell. =6

So, out of 6 octahedral voids there exists 13 which are empty. 

 So, 6×13=2 voids are not there 

So, 6-2=4 are present

Therefore, the formula of the metal oxide will be M4O6 or M2O3.

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