Q.

In a one-litre flask, 6 moles of A undergoes the reaction AgPg.  The progress of product formation at two temperatures (in Kelvin), T1 and  T2 is shown in the figure:
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If T1=2T2andΔG2ΘΔG1Θ=RT2lnx,  then the value of x  is ___.
[ΔG1Θand ΔG2Θare standard Gibb’s free energy change for the reaction at temperatures  T1 and T2  respectively.]

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answer is 8.

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Detailed Solution

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T1APt=0;6 0t=;6 0KT1=2 T2APt=0 6 0t=4 2KT2=12ΔG20ΔG10=RT2ln2R2T2ln12=RT2ln8 x=8 

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In a one-litre flask, 6 moles of A undergoes the reaction Ag⇌Pg.  The progress of product formation at two temperatures (in Kelvin), T1 and  T2 is shown in the figure:If T1=2T2 and ΔG2Θ−ΔG1Θ=RT2 lnx,  then the value of x  is ___.[ΔG1Θand ΔG2Θare standard Gibb’s free energy change for the reaction at temperatures  T1 and T2  respectively.]