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Q.

In a reaction at equilibrium ‘X’ moles of the reactant A decomposes to give 1 mole each of C and D. If the fraction of A decomposed at equilibrium is independent of initial concentration of A then the value ‘X’ is 

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a

2

b

1

c

3

d

4

answer is B.

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Detailed Solution

      xA      C  +  D

       a            0       0     at initial

a(1 - a)        x   x    at equilibrium

K=C DAx  =  α2 a2x2v2a 1-αVx

                =α2a2-αx21-αxV2-x

     α  is  independent  of A  2-x=0  or  x=2

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