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Q.

In a reaction between A and B the initial rate of reaction(r0) was measured for different initial concentrations of A and B as given below:

Experiment number [A] mol /lit[B] mol /litRate of reaction (mole/lit/sec)
I0.200.305.07×10-5
II0.200.105.07×10-5
III0.400.051.014×10-4

Identify incorrect statement(s) about the given reaction

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a

Order with respect to A is 1 

b

Order with respect to A is zero 

c

Order with respect to B is 1 

d

Order with respect to B is zero

answer is B, C.

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Detailed Solution

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r1 = [0.20]p[0.30]q = 5.07 ×10-5

r2 = [0.20]p[0.10]q = 5.07 ×10-5

r3 = [0.40]p[0.05]q = 1.014 ×10-4 

on solving rate [A]1[B]0

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