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Q.

In a reversible reaction Kc > Kp and  H= + 40 K.Cal. The product will be obtained in less amount on

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a

Decreasing pressure & increasing temperature

b

Increasing pressure & decreasing temperature

c

Increasing both pressure & temperature

d

Decreasing both pressure & temperature

answer is B.

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Detailed Solution

Given KC > KP. This indicates Δn = negative nP(g) < nR(g)

Thus forward reaction is favoured at high pressure

\large \because \Delta H = +40K cals (endothermic), High temperature favours forward reaction.

Product obtained is less when

Temperature is low

Pressure is low

 

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