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Q.

In acidic medium one mole KMnO4can oxidize Y moles of FeC2O4. Value of  Y is 

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a

0.6

b

0.5

c

1.67

d

2

answer is C.

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Detailed Solution

MnO4-Mn+2; +7            +2; n-factor=5; In ferrous oxalate both ferrous ion and oxalate ion get oxidized; Fe+2Fe+3( increase in ox.state=1);  C2+3O4-2C+4O2(total increase in ox.state=2); n-factor=3; Thus 3 moles of KMnO4 can oxidize 5 moles of FeC2O4; 

 

 

 

 

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