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Q.

In acidic medium the rate of reaction between BrO3- and Br ion is given by the expression

d(BrO3-)dt=K [BrO3-]  [Br]  [H+]2

Which of the following is correct?

 

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a

Doubling the concentration of H+ ions will increase the reaction rate by 4 times.

b

Rate constant of overall reaction is 4 sec.

c

Rate of reaction is independent of the conc. of acid

d

The change in pH of the solution will not affect the rate.

answer is A.

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Detailed Solution

For the reaction,

d[BrO3-]dt=K [BrO3-] [Br] [H+]2

The rate law equation indicates that it depends on the concentration of BrO3-, Br- and twice the concentration of H+. This indicates that the rate affects by the concentration of acid and change in pH of the solution. It also signifies that if concentration [H+] becomes twice, then the rate becomes four times.

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