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Q.

In an aqueous solution of Fe (III) and (SCN), the equilibrium can be represented as follows: Fe(aq)3+Pale yellow         +        SCN(aq)Colourless[Fe(NCS)](aq)2+red For this choose correct statements 

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a

When KSCN is added to it there is no change in colour 

b

When oxalic acid is added, there is a decrease in red colour

c

When HgCl2(aq) is added the red colour disappears 

d

When FeCl3is added to it there is no change in colour

answer is C, D.

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Detailed Solution

Oxalic acid form stable complex with Fe3+ than SCN so equilibrium shifts backward similarly Hg2+ form stable complex.  

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