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Q.

In an aqueous solution of volume 500 ml, when the reaction of 2Ag+  +  Cu      Cu2+  +  2Ag reached equilibrium the Cu2+ was x M. When 500 ml of water is further added, at the equilibrium Cu2+ will be

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a

2x  M

b

x  M

c

between x M and x/2 M

d

less than x/2 M

answer is D.

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Detailed Solution

2Ag+  +  Cu      Cu2+  +  2Ag

a M                           x M          if V is 500 ml

If volume is doubled, then for KC=xa2 to have same value Cu2+ will be less than x/2

 

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