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Q.

In an evacuated vessel of capacity 112 L, 4 moles of Ar(g) and 5 moles of PCl5(g) were introduced and the temperature is maintained at 273°C. At equilibrium, the total pressure of the mixture was found to be 4.8 atm.

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a

KP for the reaction : PCl5(g)PCl3(g)+Cl2(g) is 2.7 atm

b

At equilibrium, the total moles of gases are 12

c

The degree of dissociation of PCl5(g) into PCl3(g) and Cl2(g) is 0.6

d

On removing Ar(g) from the equilibrium mixture at constant pressure and temperature, the extent of dissociation of PCl5 will increase

answer is A, C.

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