Q.

In an experiment, 50 mL of 0.1M solution of a salt reacted with 25 mL of 0.1M solution of sodium sulphite. The half equation for the oxidation of sulphite ion is :
SO32(aq)+H2OSO42(aq)+2H++2e
If the oxidation number of metal in the salt was 3 , what would be the new oxidation number of metal?

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a

2

b

1

c

0

d

4

answer is C.

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Detailed Solution

The value of n can be calculated as,

50×0.1×n=25×0.1×2n=1

Thus, the new oxidation number is

 O.N. =+31=+2

Thus, the correct option is C.

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