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Q.

In an experiment, 1.0 g of lime stone (CaCO3) gave 224 cm3 of CO2 at NTP and 0.56 g of calcium oxide. These data illustrate the law of: 

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a

Multiple proportion

b

Reciprocal proportion

c

Gaseous volume 

d

Conservation of mass. 

answer is D.

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Detailed Solution

CaCO3CaO+CO2 gas 

                 0.56g 22400cm3

wt. of CaCO3=1.0g                 …(1)

wt. of CaO=0.56g

22400cm3CO2 weighs = g. mol. wt. of CO2

                   =12+(2×16)=44g

 224cm3CO2 weighs =44g22400×224=0.44g

 wt. of products =0.56+0.44=1.0g

wt. of reactant CaCO3=1.0g

Since the weight of reactants is equal to that of products, the law of conservation of mass is obeyed. So, the correct answer is (d).

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