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Q.

In an ionic substance, mole ratio of cation to anion is 1 : 2. If atomic mass of metal cation and non-metal anion respectively are 138 and 19 amu then, the most correct statement preferentially is

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a

molecular mass of compound is 176 amu

b

molecular mass of substance is 157 amu

c

formula mass of compound is 157 amu

d

formula mass of substance is 176 amu

answer is B.

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Detailed Solution

Mass of Metal cation (A) is 138 amu

Mass of Non-metal anion (B) is 19 amu

The mole ratio of cation to anion is 1:2 implies the formula of ionic substance is AB2

The formula mass of the substance =138+(19×2)=176 amu 

Ionic substances should not be called as ‘compounds’ as they do not contain discrete molecules. Mass of such a substance has to be referred as ‘Formula Mass’ and not  as ‘Molecular Mass’ 

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