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Q.

In a SN2 substitution reaction of the type 

RBr+ClDMFRCl+Br

Which one of the following has the highest relative rate?

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a

CH3CH2CH2Br

b

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c

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d

CH3CH2Br

answer is B.

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Detailed Solution

SN2 mechanism is followed in case of primary and secondary alkyl halides i.e SN2 reaction is favoured by small groups on the carbon atoms attached the halogen so Primary is more reactive than secondary and tertiary alkyl halides

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In a SN2 substitution reaction of the type R−Br+Cl−→DMFR−Cl+Br−Which one of the following has the highest relative rate?