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Q.

In B2H6, two H atoms complete octets of two B-atoms oscillation between them taking the electrons of the bonds formed. These bonds are called

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a

banana bonds

b

3C – 2e bonds

c

hydrogen bridge bonds

d

all of these

answer is D.

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Detailed Solution

  • Diborane is an electron deficient compound. In diborane, total number of valence electrons is 12.
  •  Diborane contains two coplanar BH2 groups. 
  • Diborane has four terminal hydrogen atoms and the two boron atoms lie in one plane. 
  • Above and below this plane, there are two bridge hydrogen atoms.
  •  The bridge hydrogen atoms are present in a plane perpendicular to rest of the molecule. 
  • Each bridge hydrogen is bonded to the two boron atoms only by sharing of two electrons. 
  • These are called three centered two electron 3c-2e- bonds, also known as banana or tau bonds. 
  • The terminal B−H bonds are 2c-2e- bonds.
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