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Q.

In base vs. Acid titration, near the end point methyl orange is present as ________ in basic medium

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a

phenolic form

b

heterocyclic form

c

benzenoid form

d

quinonoid form

answer is D.

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Detailed Solution

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Explanation:

Methyl Orange is a pH indicator used in acid-base titrations. It exhibits different colors in acidic and basic mediums due to its structural changes:

  • In an acidic medium (low pH), it exists in the quinonoid form, appearing red.
  • In a basic medium (high pH), it converts to its benzenoid form, appearing yellow.

At the end point of a base vs. acid titration, when the medium is basic, methyl orange is present in its benzenoid form.

Answer: In basic medium, near the end point, methyl orange is present as benzenoid form.

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