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Q.

In Carius method for estimation of halogens, 0.2g of an organic compound gave 0.188 g of AgBr. The percentage of bromine in the compound is . (Nearest integer) [Atomic mass : Ag = 108, Br = 80]

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a

37

b

39

c

38

d

40

answer is D.

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Detailed Solution

Given data:

           Mass of organic compound = 0.2 g
           Mass of AgBr = 0.188 g

To find = Percentage of bromine .

Explanation:

We know, Molar mass of AgBr = 188 g mol-1
In 1 mole of AgBr, bromine content = 80 g mol-1
In 1 g of AgBr, bromine content = 80188g mol-1
In 0.188 g of AgBr, bromine content = 80188×0.188 g mol-1
Percentage of bromine in the given compound = 80188×0.188×10.2×100 % = 40 % (approx)

Hence, the correct option is option (D) 40.

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