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Q.

In context with the transition elements, which of the following statements is incorrect?

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a

In the highest oxidation of the first five transition elements (Sc to Mn), all the 4s and 3d electrons are used for bonding?

b

Once the ,d5 configuration is exceeded the tendency to involve all the3d electron bonding decrease.

c

In addition to the normal oxidation  state the zero oxidation  state  is also shown by these elements in complexes.

d

In the highest oxidation state , the transition  metal show basic character and form cationic  complexes.

answer is D.

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Detailed Solution

Transition metals produce anionic complexes rather than cationic ones at the highest oxidation states.

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