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Q.

In conversion of lime-stone to lime, CaCO3(s)CaO(s)+CO2(g) he values of ΔH and ΔS are 179.1kJmol-1 and 160.2JK1mol1 respectively at 298 K and 1 bar. Assuming that  ΔHand ΔSdo not change with temperature, temperature above which conversion of limestone to lime will be spontaneous is

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a

1118 K

b

1008 K

c

1200 K

d

845 K 

answer is D.

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Detailed Solution

The temperature at which given reaction exists as equilibrium is

Teq =ΔHΔS=179.1×103mol1160.2JK1mol1=1118K

At T>Teq,ΔGof the reaction will be negative and hence the given reaction will be spontaneous.

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