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Q.

In conversion of limestone to lime, CaCO3(s)CaO(s)+CO2(g).  The values of  ΔH0 and ΔS0  are +179.1 kJ/mol and 160.2 J/K respectively at 298K and 1 bar. Assuming that  ΔH0 and ΔS0   do not change with temperature above which conversion of limestone to lime will be spontaneous

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a

845 K

b

1118 K

c

1008 K

d

1200 K

answer is D.

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Detailed Solution

ΔG=ΔH-TΔS

So, let’s find the equilibrium temperature, i.e., at which ΔG=0,ΔH=TΔS

T=179.1×1000160.2=1118K

So, at the above temperature the reaction will become spontaneous.

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