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Q.

In cyanide extraction process of silver from argentite ore, the oxidizing and reducing agents are respectively.

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a

O2 and CO2

b

O2 and Zn dust

c

HNO3 and Zn dust

d

HNO3 and CO

answer is B.

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Detailed Solution

The reactions involved in extraction of silver by cyanide process are
Ag2S+CN+O2 ⟶ [Ag(CN)2] + SO2 ...........(i)

[Ag(CN)2] + Zn ⟶ [ Zn(CN)4]2+ Ag........(ii)

In reaction (i), sulphide is oxidised to SO2 by oxygen.
In the reaction (ii), silver ion (Ag+) is reduced to Ag by Zn.
Therefore,O2 is oxidising agent and Zn is reducing agent.

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In cyanide extraction process of silver from argentite ore, the oxidizing and reducing agents are respectively.