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Q.

In Friedel-Crafts alkylation of aniline, one gets

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a

alkylated product with ortho and para substitution.

b

secondary amine after acidic treatment.

c

an amide product.

d

positively charged nitrogen at benzene ring.

answer is D.

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Detailed Solution

Lewis acids are electron deficient species and nitrogen atom of aniline has a lone pair of electron. When Lewis acid reacts with aniline, then a salt forms in which nitrogen acquires a positive reaction and further reaction is not possible.

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