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Q.

In how many of the following reaction H>ΔE, assuming reaction to be occurring at a constant temperature and pressure.
(I) H2+12O2H2O(l)

(II) Combustion of C2H8(g) at 400 K

(III) Dimerisation of NO2(g)

(IV) Fusion of water a 0C

(V) Vaporisation of any liquid at its  boiling point

(VI) Dissociation of CaCO3(s)

(VII) Combustion of C2H4 at 300 K

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answer is 5.

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Detailed Solution

For the given reaction we have,
H3PO3+2NaOHΔneut Na2HPO3+2H2O(l)   ΔionH                                                   2H+           OH-                                -2×55.84

Δneut. H=Δion H2×55.84Δion H=5 kJ

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