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Q.

In hydrogen atom wavelength of second line of Balmer series is λ, which of the following statement(s) is/are correct:
A) The wavelength of the First line of Balmer series is (2720)λ
B) The wavelength of the Third line of Balmer series is  (2015)λ
C) The wavelength of the First line of Lyman series is  (λ4)
D) The wavelength of the Second line of Lyman series is  (2512)λ

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a

A, B, C,D

b

A, C, D 

c

B, C,D

d

A, C

answer is B.

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Detailed Solution

1λ(1n121n22)                     λ2λ1=(1/n121/n22)i(1/n121/n22)f                        λ2=(1/41/16)λ(1/n121/n22)f                        λ2=(316λ)[1(1/n121/n22)f]

A) For first line of Balmer series, 
  n1=2,n2=3
                     λ2=(2720)λ
B) For third line of Balmer series, 
  n1=2,n2=5
              λ5=(2528)λ
C) For first line of Lyman series, 
  n1=1,n2=2
            λ2=λ4
D) For second line of Lyman series, 

n1=2,n2=3

         λ2=(27128)λ

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