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Q.

In iodometric estimation of Cu2+ ion the following reactions took place

2Cu2++4ICu2I2+I2 I2+2Na2S2O32NaI+Na2S4O6

If 100 mL of CuSO4solution added to excess KI requires 50 mL of 0.2 M  Na,S2O3 the molarity of CuSO4 solution is:

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a

0.25M

b

0.05M

c

0.1M

d

0.2M

answer is D.

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Detailed Solution

The molarity of copper sulphate solution can be calculated as,

50×0.2×1=100×M×1

Thus, M =0.25M

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