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Q.

In Lyman series, shortest wavelength of H-atom appears at x meter , then longest wavelength in Balmer series of He+ appear at

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a

9x5m

b

x4m

c

5x9

d

36x5m

answer is A.

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Detailed Solution

For the spectral line in H-atom and H-like species (one electron) 

1λ=v¯=R¯HZ21n121n22

For Lyman series

For shortest wavelength (maximum wave number) n2

         1λmin=vmax=R¯H(1)211

For longest wavelength (minimum wave number), n2=n1+1

For Balmer series, n1=2

        1λmax=vmin=RH(Z)212

For He+ , Z = 2

1λmax=1x(2)25361λmax=59x    λmax=9x5

 

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