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Q.

In methyl alcohol solution, bromine reacts with ethylene to yield BrCH2CH2OCH3 in addition to 1, 2-dibromoethane because

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a

Intermediate may react with Br- or CH3OH

b

The methyl alcohol solvates the bromine

c

The reaction follows Markownikoff's rule

d

This is a free-radical mechanism

answer is A.

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Detailed Solution

When ethylene reacts with Br2, then first there is the formation of a cyclic intermediate. At that instance, both Br- and -CH3O- (from CH3OH) attack on the cyclic intermediate. Therefore, 2 products are expected instead of one.

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In methyl alcohol solution, bromine reacts with ethylene to yield BrCH2CH2OCH3 in addition to 1, 2-dibromoethane because