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Q.

In nitrogen family the H–M–H bond angle in the hydrides MH3 gradually becomes closer to 90oC on going from N to Sb. This shows that gradually :

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a

Almost pure p-orbitals are used for M–H bonding

b

This basic strength of the hydrides increases

c

The bond pairs of electrons become further apart form the central atom

d

The bond energies of M–H bond increase

answer is B, D.

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Detailed Solution

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From ammonia to SbH3 bond angle approaches a value of 90°. This indicates in NH3 - orbitals involved in hybridisation while in going down the group pure p-orbitals are participating in bonding.

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