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Q.

In order that a compound may show geometrical isomerism

A) Compound must have a chiral carbon
B) Each of the two doubly bonded carbon atoms must have different atoms or groups
C) Compound must have a plane of symmetry

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a

 only C

b

only A

c

 only B  

d

None

answer is B.

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Detailed Solution

C1 and C2 carbon groups can be or cannot be same.

Geometrical isomerism is not possible if C1 or C2 two groups are same.

So in the four group they exhibit.

Ca2 = Cb2     C1 aa =C2bb     No geometrical isomerism  Ca2  =Cab             aaC1 = Cba2   No geometrical isomerism  Cab = Cab               C ba = Cba       Exhibits Geometrical Isomerismit geometrical isomerism.

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