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Q.

In order to cause the coagulation of 100 ml Arsenious sulphide solution, 111.7 mg of 2 M NaCl solution is used. What will be the coagulation value of NaCl?

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Detailed Solution

Flocculation value is the number of millimoles of the electrolyte needed for 1 litre of the colloidal solution.
Assuming 1 litre of the solution,
mass of 1litre of 2 m NaCl = 1000×1.117 = 1117 g.
Moles of NaCl = 2
Mass of NaCl present in 1117 g of the solution = 2 × 58.5 = 117 g
Mass of NaCl present in 111.7 mg of the solution is 117 × 0.11171117= 0.0117 g =11.7 mg
milli-moles of NaCl = 11.758.5=0.2

0.2 milli-moles of NaCl required for 100 mL of the solution
Millimoles of NaCl for 1 L of the arsenious sulphide solution
0.2100×1000 = 2

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In order to cause the coagulation of 100 ml Arsenious sulphide solution, 111.7 mg of 2 M NaCl solution is used. What will be the coagulation value of NaCl?