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Q.

In order to concentrate galena (which contains ZnS as impurity) by froth-floatation process, sodium cyanide is used as depressant. NaCN dissolves ZnS due to formation of water soluble complex(A). Find wxyz, 

where w = coordination number of central metaion. in complex ion of (A)

x = number of unpaired electrons in (A)

y = total number of possible linkage isomers of (A) including (A)

z = maximum number of atoms in a single plane in the complex ion of {A)

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answer is 4055.

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Detailed Solution

The reaction and complex formed is :

ANa2Zn(CN)4(sp3);

It is a tetrahedral compound of zinc that is seen above. Zn has an oxidation state of +2 and a coordination number of 4. As a result, it has no unpaired electrons and a 3d104s0 configuration.
Cyanide, symbol CN, is an ambidentate ligand. Both the C end and the N end can connect together to form a bond. Therefore, there will be five potential connection isomers.
One plane can include up to five atoms, so take the plane that passes through the two atoms of CN (which are in the plane) and the central atom Zn as an example.

So,

w=4,x=0,y=5,z=5

Hence, W+x+y+z=14

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