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Q.

In order to estimate  O3 in the air , 22.4L of air at 1atm and 0oC, is passed through acidified KI  solution where  O2 is evolved and I-  is oxidized to I2. The liberated  I2  required 200mL of 0.1M Na2S2O3  in acidic medium, then what will be the % composition of  O3  by volume in the sample?

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Detailed Solution

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 2Kl+O3+H2O2KO2+l2+O2
Meg of  I2=Meg  of  Na2S2O3=200×0.1=20
 m moles of  I2=megvalecy=202=10
Also millennials of  O3 = millennials I2  (mole ration = 1 : 1) 
 Millennials = 10 of   O3
or  moles  =10 ×103
  P=nRT/v Po3=10×103×0.082×27322.4 Po3%=10×103×100 =1%   
 

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