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Q.

In orthorhombic crystal system , the value of a, b and c are respectively 4.2A0,8.6A0 and 8.3A0. Given the molecular mass of the solute is 155 gm mol-1 and that of density is 3.3 gm/cc, the number of formula units per unit cell is 

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a

2

b

3

c

4

d

6

answer is C.

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Detailed Solution

d = ZMN0a3    a3 = V=a×b×c

Z=V×N0×dM

=4.2×8.6×8.3×10-24×6.023×1023×3.3155

=3.84~4

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